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CPID

Health effects of consumer products

Pyroil R-134A Refrigerant

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  1,1,1,2-Tetrafluoroethane	000811-97-2	100		No
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  1,1,1,2-Tetrafluoroethane

  000811-97-2

  212-377-0

  100

  H280 P410+P403 No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • View Material Safety Data Sheet(MSDS)

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      July 06, 2000

    • Date when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified. MSDS Verified :

      April 04, 2006

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	1	0	1

    • Acute health effects

      From MSDS
      HAZARDS IDENTIFICATION
      Primary Route(s) of Entry:  Inhalation, Skin contact.
      Potential Health Effects
      Eye: Can cause eye irritation.
      Skin: Causes burns and frostbite.
      Swallowing: Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury.
      Inhalation: Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful.
      Symptoms of Exposure: stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness), and death.

    • Chronic health effects

      From MSDS
      No information provided.

    • Carcinogenicity

      No data.

    • Handling information

      Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. This is a high-pressure gas. Use piping and equipment adequately designed to withstand pressures to be encountered. Use with adequate ventilation. Close valve when not in use and when cylinder is empty. Always use a suitable hand truck or similar device for moving gas cylinders. Firmly secure cylinders during transport. Do not lift or move a cylinder by the cap. Do not roll or drag a cylinder to move it or allow cylinders to strike each other or any surface violently. Never tamper with or attempt to repair or alter cylinders, valves or any safety relief devices. Do not attempt to remove a stuck cap by using a lever in the cap ports. This may accidentally open the valve when the cap turns. Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, and then repair the leak. Be sure to read and understand all labels and other instructions supplied with all containers of this product. For safety information on general handling of compressed gas cylinders, it is recommended that a copy of Pamphlet P-1, Safe Handling of Compressed Gases in Containers, be obtained from the Compressed Gas Association, Inc.
      Store cylinders upright and secured in a well-protected, well-ventilated, dry location away from heavy traffic and emergency exits. Do not allow the temperature where cylinders are stored to exceed 125 degrees F (52 degrees C). Store cylinders at least 20 feet away from highly combustible materials, and away from any sparks, flames, or any other source of heat or ignition. Protect cylinders from physical damage. Assigned storage places should be located where cylinders will not be knocked over or damaged by passing or falling objects. Segregate full and empty cylinders. Prevent full cylinders from being stored for excessive periods of time. If gas cylinders were designed to have valve caps, keep caps on and hand-tight at all times when cylinders are not in use or connected for use. Caps are for valve protection ONLY.

    • Disposal information

      Return to supplier for reclamation.

    • First Aid

      Eyes: If material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes while holding eyelids apart. If symptoms develop as a result of vapor exposure, immediately move individual away from exposure and into fresh air before flushing as recommended above. Seek immediate medical attention.
      Skin: Treat burned or frostbitten skin by flushing the exposed area with lukewarm water. Seek immediate medical attention.
      Swallowing: Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
      Inhalation: If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.
      Note to Physicians: Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. This material is an aspiration hazard. Potential danger from aspiration must be weighed against possible oral toxicity when deciding whether to induce vomiting.